William George Armstrong to Faraday   22 October 1840

Newcastle-upon-Tyne, Oct. 22, 1840.

Dear Sir, - I yesterday revisited the boiler at Seghill, in company with some friends, and took with me such apparatus as I deemed necessary for experimenting on the electrical steam. The results of this second visit I now hasten to com‑municate, and you will find in the following account of my proceedings, answers to all the queries you were kind enough to send me1, for the purpose of directing my attention to the proper points of inquiry.

I found the boiler, and everything connected with it, precisely in the state which I have already described it, and on trying the steam in the same way as I did on the former occasion, the effect was very nearly the same; but when I placed myself on an insulating stool, the intensity of the sparks which passed between my hand and the boiler was greatly increased, as well as the twitching sensation in the knuckles and wrist, which accompanied the operation, and which in my former letter I designated a slight electrical shock. In pursuance of your instructions, I had provided myself with a brass plate, having a copper wire attached to it, which terminated in a round brass knob. When this plate was held in the steam by means of an insulated handle, and the brass knob brought within about a quarter of an inch from the boiler, the number of sparks which passed in a minute was from sixty to seventy, as nearly as we could count; and when the knob was advanced about one-sixteenth of an inch nearer to the boiler, the stream of electricity be‑came quite continuous. The greatest distance between the knob and the boiler, at which a spark would pass from one to the other, was fully an inch. A Florence flask, coated with brass filings on both surfaces, was charged to such a degree with the sparks from the knob, as to cause a spontaneous discharge through the glass; and several robust men received a severe shock from a small Leyden jar charged by the same process. The strength of the sparks was quite as great when the knob was presented to any conductor communicating with the ground, as when it was held to the boiler. It appeared to make very little difference in what part of the jet the plate attached to the conducting wire was held; but when a thick iron wire was substituted for the plate, the effect was greatest when the wire was held very near to the orifice. The valve was loaded at the rate of thirty-five pounds per square inch; but the pressure of the steam fluctuated considerably, which gave me an opportunity of observing that the quantity of electricity derived from the jet increased and diminished with the pressure. The electricity of the steam was positive; for when the pith balls of the electrometer diverged upon an instrument connected with the steam, they were at‑tracted by a piece of sealing-wax rubbed on woollen cloth; and when a pointed wire was held by the person on the stool, under the shade of a hat, a pencil, and not a star, of electrical light became visible.

Besides the principal jet of steam which I operated upon, there were several small streams issuing from different parts of the boiler, and in each of these the electrometer indicated the presence of electricity. From the peculiar manner in which the steam blew off from the safety-valve when the weight on the lever was lifted, it was quite impossible to try any satisfactory experiment upon the steam which was allowed to escape by that means. I applied the gold-leaf electrometer to vari‑ous parts of the boiler, which, I ought to observe, is in direct communication with the ground by means of the steam-pipes, but could scarcely detect a trace of electricity in any part of it.

The engine has another boiler besides the one in question, and the two boilers lie immediately adjacent to each other. Having been informed that similar phaenomena had been discovered in this second boiler, I proceeded to apply the elec‑trometer to some small pencils of steam which were escaping in different parts, and found the same indications which I had observed under similar circumstances in the first boiler. I then raised the safety-valve, and the column of steam which escaped from it proved as highly charged with electricity as the horizontal jet which issued from the other boiler, and in which the phaenomenon had first been observed.

Upon inquiry, I found that the water used in the boilers was obtained from a neighbouring colliery, where it was pumped out of the mine, and that the same water was used for the boiler of a small high-pressure engine adjoining the colliery from which the water was procured. In order, there‑fore, to form an opinion whether or not the phaenomenon in question was dependent upon the quality of the water from which the steam was generated, I proceeded to examine the steam evolved from the boiler to which I had been referred, and which proved to be a very small one. The valve was loaded with only twenty pounds on the square inch, and I learned from the engine-man that no appearance of electricity had ever been noticed in the steam. Upon trial, however, I succeeded in obtaining very distinct sparks of electricity from the column of steam which issued from the safety-valve. The sparks were certainly weaker than those obtained at the other engine, but this may reasonably be ascribed to the inferior pressure of the steam, and smaller size of the boiler.

I then repaired to another high-pressure engine, which belonged to the same establishment, and the boiler of which was supplied with rain water instead of that drawn from the mine. In this case the pressure of the steam was forty pounds on the square inch. The valve was inaccessible, but a powerful jet of steam was obtained from the upper gauge-cock; I could not, however, obtain any trace of electricity in the steam from this boiler, not even sufficient sensibly to affect the gold-leaf electrometer. The presumption, then, is exceedingly strong, that the phaenomenon is in some way occasioned by the peculiar nature of the water from which the steam is produced. I inclose you a specimen of the incrustation2, of a month's growth, deposited by the water from the mine in the boilers in which it is used.

I shall be glad to receive any further instructions from you as to the proper mode of pursuing the investigation, and should be much gratified to hear your opinion as to the cause of this most curious phaenomenon3.

I am, dear sir, | Very respectfully yours, | H. [sic] G. Armstrong

M. Faraday, Esq.

Faraday's answer to letter 1315 has not been found. See letter 1320 and Faraday (1843a), ERE18.
Note by Faraday at this point: "The incrustation is grey and hard; it contains traces of a soluble muriate and sulphate, but consists almost entirely of sulphate of lime, with a little oxide of iron and insoluble clayey matter, carried in probably by the water. There is hardly a trace of carbonate of lime in it. - M.F.".
Note by Faraday at this point: "The evolution of electricity by vaporization, described by Mr. Arm‑strong, is most likely the same as that already known to philosophers on a much smaller scale, and about which there are as yet doubts whether it is to be referred to mere evaporation, as Harris says [Harris (1834), 241-2], or to chemical action, according to others. This point it neither settles nor illustrates; but it gives us the evolution of electricity during the conversion of water into vapour, upon an enormous scale, and therefore brings us much nearer to the electric phaenomena of volcanos, water-spouts and thunder-storms, than before. - M.F.".

Bibliography

FARADAY, Michael (1843a): “Experimental Researches in Electricity. -Eighteenth Series. On the electricity evolved by the friction of water and steam against other bodies”, Phil. Trans., 133: 17-32.

Please cite as “Faraday1317,” in Ɛpsilon: The Michael Faraday Collection accessed on 28 April 2024, https://epsilon.ac.uk/view/faraday/letters/Faraday1317